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2 article(s) from Schröder, Hendrik V

Thermodynamic and electrochemical study of tailor-made crown ethers for redox-switchable (pseudo)rotaxanes

Henrik Hupatz,
Marius Gaedke,
Hendrik V. Schröder,
Julia Beerhues,
Arto Valkonen,
Fabian Klautzsch,
Sebastian Müller,
Felix Witte,
Kari Rissanen,
Biprajit Sarkar and
Christoph A. Schalley

Beilstein J. Org. Chem. 2020, 16, 2576–2588, doi:10.3762/bjoc.16.209

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Graphical Abstract

Figure 1: Structures of the compounds used in this study: a) crown-8 analogs; b) crown-7 analogs; c) secondar...

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Scheme 1: Schematic representation of synthetic routes towards TTFC7, exTTFC7, NDIC7, and NDIC8.

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Figure 2: Solid-state structures of a) exTTFC7 (CH₃CN molecule omitted for clarity), b) NDIC7 (CH₃CN molecule...

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Figure 3: a) Synthesis of the [2]rotaxane NDIRot. b) Stacked ¹H NMR spectra (700 MHz, CDCl₃, 298 K) of NDIC8 ...

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Figure 4: UV–vis–NIR spectra obtained by spectroelectrochemical measurements (0.1 M n-Bu₄PF₆, CH₂Cl₂/CH₃CN 1:...

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Full Research Paper

Published 20 Oct 2020

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Tetrathiafulvalene – a redox-switchable building block to control motion in mechanically interlocked molecules

Hendrik V. Schröder and
Christoph A. Schalley

Beilstein J. Org. Chem. 2018, 14, 2163–2185, doi:10.3762/bjoc.14.190

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Figure 1: The two one-electron oxidation reactions of tetrathiafulvalene (TTF, 1) and the corresponding prope...

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Figure 2: UV–vis spectra and photographs of TTF 2 in its three stable oxidation states (black line = 2, orang...

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Figure 3: Structure and conformations of two TTF dimers in solution, the mixed-valence and the radical-cation...

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Figure 4: (a) The isomerism problem of TTF. (b)–(d) Major synthetic breakthroughs for the construction of TTF...

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Figure 5: (a) Host–guest equilibrium between π-electron-poor cyclophane 3 and different TTFs with their corre...

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Figure 6: TTF complexes with different host molecules.

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Figure 7: Stable TTF (a) radical-cation and (b) mixed-valence dimers in confined molecular spaces.

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Figure 8: A “three-pole supramolecular switch”: Controlled by its oxidation state, TTF (1) jumps back and for...

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Figure 9: Redox-controlled closing and opening motion of the artificial molecular lasso 12.

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Figure 10: Graphical illustration how a non-degenerate TTF-based shuttle works under electrochemical operation....

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Figure 11: The first TTF-based rotaxane 13.

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Figure 12: A redox-switchable bistable molecular shuttle 14.

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Figure 13: The redox-switchable cyclodextrin-based rotaxane 15.

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Figure 14: The redox-switchable non-ionic rotaxane 16 with a pyromellitic diimide macrocycle.

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Figure 15: The redox-switchable TTF rotaxane 17 based on a crown/ammonium binding motif.

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Figure 16: Structure and operation of the electro- and photochemically switchable rotaxane 18 which acts as po...

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Figure 17: (a) The redox-switchable rotaxane 19 with a donor–acceptor pair which is stable in five different s...

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Figure 18: Schematic representation of a molecular electronic memory based on a bistable TTF-based rotaxane. (...

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Figure 19: Schematic representation of bending motion of a microcantilever beam with gold surface induced by o...

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Figure 20: TTF-dimer interactions in a redox-switchable tripodal [4]rotaxane 22.

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Figure 21: (a) A molecular friction clutch 23 which can be operated by electrochemical stimuli. (b) Schematic ...

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Figure 22: Fusion between rotaxane and catenane: a [3]rotacatenane 24 which can stabilize TTF dimers.

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Figure 23: The first TTF-based catenane 25.

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Figure 24: Electrochemically controlled circumrotation of the bistable catenane 26.

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Figure 25: A tristable switch based on the redox-active [2]catenane 27 with three different stations.

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Figure 26: Structure of catenane-functionalized MOF NU-1000 [108] with structural representation of subcomponents. ...

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Figure 27: (a) [3]Catenanes 29 and 30 which can stabilize mixed-valence or radical-cation dimers of TTF. (b) S...

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Review

Published 20 Aug 2018

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